Comparison and development of new extraction procedures for 239Pu, Ca, Fe and Cu organic complexes in soil

Gyula Szabo, Angela J. Wedgwood, Robert Bulman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Two new extraction methods-the silylation of the organic constituents of soil with trimethylchlorosilane (TMCS) and triethylchlorosilane (TECS) in the presence of dimethylformamide (DMF)-have been developed for mobilization of the organic complexes of Ca, Fe, Cu and Pu which might exist in some soils. By silylation of the carboxylic, phenolic, alcoholic and perhaps the amino moieties of humic and fulvic acids (the principal organic constituents of soils) the authors have modified the solubility of the humic substances with perhaps a minimum perturbation of the humate-metal ion complexes. These new extraction procedures, which use a non-aqueous solvent, have been compared with a variety of aqueous extraction procedures (sodium hydroxide, 1 m potassium chloride and diethylenetriaminepentaacetic acid solution) and found to be superior in the release of the elements from soils.

Original languageEnglish
Pages (from-to)181-189
Number of pages9
JournalJournal of Environmental Radioactivity
Volume13
Issue number3
DOIs
Publication statusPublished - 1991

Bibliographical note

Funding Information:
Gy. Szabow asthe gratefurl ecipienot f a trainingfe llowshipt,h et enureo f which was held at the NationalR adiologicaPl rotectionB oard,from the InternationaAlt omicE nergyA gency.T his work wass upporteidn part by the Commissiono f the EuropeanC ommunityu, nderc ontractB IG-B-048-UK.

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